Resilient and Reversible Phosphotungstic Acid Passivated Zinc Anode

Aqueous zinc ion batteries (ZIBs) present a compelling solution for grid-scale energy storage, which is crucial for integrating renewable energy resources into the electric infrastructure. The cycling stability of ZIBs hinges on the electrochemical reversibility of the zinc anode, which is often compromised by corrosion and dendritic zinc deposition. Here, we present a straightforward surface passivation strategy that significantly enhances the cycling stability of zinc anodes. By immersing zinc in a solution of phosphotungstic acid, we promoted the dominance of the 002 plane of zinc's hexagonal structure. This process facilitates the creation of a uniform nucleation and protective layer on the native zinc surface, resulting in a more uniform plating-stripping process and increased corrosion resistance. In symmetric cells, the passivated zinc exhibits a capacity retention of 68.7% after 1000 cycles at a current density of 1.0 Ag