Intrinsically morphological effect of perovskite BaTiO3 boosting piezocatalytic uranium extraction efficiency and mechanism investigation

Developing a convenient, efficient and eco-friendly approach for the recovery of U(VI) ion is a key measure to solve the environmental problems arising from the utilization of nuclear energy. Herein, the high efficiency of uranium extraction is realized by the piezo property of perovskite BaTiO3, revealing the intrinsically morphological engineering effect on the piezocatalytic performance. Especially, BaTiO3 nanowires (BTO NWs) exhibit not only an excellent piezocatalytic activity with U(VI) extraction rate of 96.8% in a UO2(NO3)2 aqueous solution compared to 71.3% of BaTiO3 nanoparticles (BTO NPs), but also a promising piezocatalyst for U extraction in a real U-mining wastewater with various pH ranges. Piezo response force microscopy and finite elemental simulation show that the piezo response of BTO NWs is much higher than BTO NPs. Additionally, some factors (pH, various ions, different powers) are explored on piezocatalytic efficiency for U(VI) extraction. The results from electron spin resonance and the charge/radical capture experiments confirm that the active species (e-, •O2-, •OH) stemmed from the piezo induction of BTO NWs and BTO NPs in the piezocatalytic U(VI) reduction process. The present work reveals the structure-performance correlation during piezocatalysis and highlights the crucial role of piezocatalysis in dealing with environmental problems.