材料科学
光催化
Atom(片上系统)
纳米技术
化学工程
光电子学
工程物理
光化学
催化作用
有机化学
化学
计算机科学
工程类
嵌入式系统
作者
Yue Wang,Nikita Denisov,Shanshan Qin,Danielle Santos Gonçalves,Hyesung Kim,Bidyut Bikash Sarma,Patrik Schmuki
标识
DOI:10.1002/adma.202400626
摘要
Abstract The employment of single atoms (SAs), especially Pt SAs, as co‐catalysts in photocatalytic H 2 generation has gained significant attention due to their exceptional efficiency. However, a major challenge in their application is the light‐induced agglomeration of these SAs into less active nanosized particles under photocatalytic conditions. This study addresses the stability and reactivity of Pt SAs on TiO 2 surfaces by investigating various post‐deposition annealing treatments in air, Ar, and Ar‐H 2 environments at different temperatures. We describe that annealing in an Ar‐H 2 atmosphere optimally stabilizes SA configurations, forming stable 2D rafts of assembled SAs approximately 0.5‐1 nm in diameter. These rafts not only resist light‐induced agglomeration but also exhibit significantly enhanced H 2 production efficiency. Our findings reveal a promising approach to maintaining the high reactivity of Pt SAs while overcoming the critical challenge of their stability under photocatalytic conditions. This article is protected by copyright. All rights reserved
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