扩散
钙钛矿(结构)
能量转换效率
离子
材料科学
纳米技术
化学工程
光电子学
化学
热力学
物理
工程类
有机化学
作者
Faming Han,Yazhuo Wu,Ruiqin He,Yongzheng Hui,Jun Yin,Lan‐Sun Zheng,Binghui Wu,Nanfeng Zheng
出处
期刊:Solar RRL
[Wiley]
日期:2021-01-18
卷期号:5 (3)
被引量:13
标识
DOI:10.1002/solr.202000654
摘要
Perovskite solar cells (PSCs) have attracted great interest in recent decade, however, stability issue and large‐scale application still remain as roadblocks to their practical applications. To settle aforementioned issues, metal diffusion and ion migration should be controlled to improve long‐term operational stability. Herein, cubic zinc metatitanate (ZTO) is optimized and improved by segregating with surface sulfidation. The sulfurized electron transporting layer, label as ZTO‐ZnS, based PSCs achieved an amazing power conversion efficiency (PCE) of 21.3%. A large‐area module (8.0 cm 2 active area) based on ZTO‐ZnS is also developed with 15.9% PCE. Furthermore, combining with inorganic CuI hole transporting layer and carbon counter electrode, metal diffusion, and ion migration effect are eliminated drastically in ZTO‐ZnS‐based PSCs. The combined PSC devices can easily keep more than 85% initial PCE after 1 000 h at 85 °C in air with a relative humidity of 85% under maximum power point and continuous AM 1.5G illumination. The persistence in stability is investigated and revealed fully by energy dispersive spectrometer analysis, attributing to the PSC structure which blocks the metal diffusion and ion migration in the devices. A big step forward industrialization and commercialization for PSCs is made.
科研通智能强力驱动
Strongly Powered by AbleSci AI