化学
对映选择合成
亲核细胞
环加成
催化作用
组合化学
立体化学
有机化学
出处
期刊:Synthesis
[Thieme Medical Publishers (Germany)]
日期:2018-12-03
卷期号:51 (01): 135-145
被引量:31
标识
DOI:10.1055/s-0037-1610397
摘要
This Short Review describes recent developments in cobalt-catalyzed enantioselective C–C bond-forming reactions. The article focuses on reactions that most likely involve chiral organocobalt species as crucial catalytic intermediates and their mechanistic aspects. 1 Introduction 2 Hydrovinylation 3 C–H Functionalization 4 Cycloaddition and Cyclization 5 Addition of Carbon Nucleophiles 6 Cross-Coupling 7 Conclusion
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