等结构
超分子化学
结晶学
热稳定性
戒指(化学)
金属
聚合物
水溶液
溶剂
配位复合体
晶体结构
单晶
材料科学
配位聚合物
化学
物理化学
有机化学
作者
Konstantis F. Konidaris,Christine N. Morrison,J.G. Servetas,Matti Haukka,Yanhua Lan,Annie K. Powell,John C. Plakatouras,George E. Κostakis
出处
期刊:CrystEngComm
[Royal Society of Chemistry]
日期:2012-01-01
卷期号:14 (5): 1842-1842
被引量:25
摘要
Three isostructural two-dimensional coordination polymers of the general formula [Ln2(CuL)3(H2O)9]·5.5H2O, where Ln = La (1), Nd (2), and Gd (3), have been synthesized and isolated from aqueous solutions and their single-crystal structures determined by X-ray diffraction. The supramolecular interaction between the non-aromatic metallorings plays an important role in stabilizing the structure of these compounds. The thermal stability, reversible solvent uptake, electronic properties and magnetic studies of these compounds are also reported.
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