催化作用
路易斯酸
吡啶
化学
茴香醚
吸附
打赌理论
水溶液
氨
无机化学
有机化学
作者
J. Krishna Murthy,U. Groß,Stephan Rüdiger,Erhard Kemnitz
标识
DOI:10.1016/j.apcata.2004.09.039
摘要
Fe3+ doped MgF2 catalysts are synthesized via a new two-step non-aqueous route using different Fe3+ precursors. The catalysts are characterised by BET surface area, X-ray diffraction, TPD of ammonia, FT-IR pyridine adsorption analysis and evaluated in different Lewis acid catalysed reactions viz., dismutation of CCl2F2, hydrofluorination of C2Cl4 and benzoylation of anisole. Catalysts synthesized from Fe(OCH3)3 and Mg(OCH3)2, with a surface area of 243 m2/g, high acid strength and good catalytic activity have been obtained. All the systems show a significant Lewis acid band in the FT-IR-PAS of pyridine complexes.
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