吸附
光催化
光降解
弗伦德利希方程
材料科学
化学工程
异质结
纳米-
溶剂热合成
光化学
化学
废水
核化学
有机化学
无机化学
催化作用
复合材料
废物管理
光电子学
工程类
作者
Zuyu Li,Hongchao Ma,Lihua Zang,Da Li,Shuangzhen Guo,Linglong Shi
标识
DOI:10.1016/j.seppur.2021.119355
摘要
The synergy of adsorption and photocatalysis has received considerable attention in the field of environmental remediation. In this work, a novel nano-flower MIL-125(Mo)-In2Se3 (M-In) adsorbent photocatalyst was firstly prepared by one-step solvothermal method. Benefiting from the 3D nano-flower structure, tightness 2D/2D heterojunction interface, highly exposed active site of MIL-125(Mo) and the spontaneous polarization of lamellar In2Se3, M-In exhibited an excellent adsorption and photodegradation performance in removal of tetracycline (TC) pollutants. The results of adsorption kinetic and adsorption equilibrium were well fitted by Pseudo-second-order model and Freundlich isotherm model, indicating that the adsorption progress was non-uniform and multilayer. In addition, the degradation rate of TC reached 94.14% within 120 min under visible light exposure in the presence of optimum ratio M-In-1. The results of trapping experiments, three-dimensional excitation-emission matrix (3D-EEM) fluorescence spectroscopy and liquid chromatograph-mass spectrometer showed that h+ played a significant role and O2– also played a role in the photo-degradation process. Hence, the novel adsorbent photocatalyst can be used to treat TC wastewater and the study gives some inspiration for the design and construction of efficient photocatalysts.
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