发光
磷光
荧光粉
青色
材料科学
光致发光
激发态
激发
光电子学
单重态
荧光
光化学
持续发光
化学
光学
原子物理学
热释光
物理
量子力学
作者
Mengzhu Wang,Feiyang Li,Yunxiang Lei,Fuming Xiao,Miaochang Liu,Shujuan Liu,Xiaobo Huang,Huayue Wu,Qiang Zhao
标识
DOI:10.1016/j.cej.2021.132288
摘要
The development of organic phosphors with excitation-dependent luminescence color is tremendously challenging for organic room temperature phosphorescent (ORTP) systems. Herein, we designed and synthesized a series of novel ORTP materials based on pyranone. Under the excitation of 254 nm, the materials exhibited the rare phenomenon of emitting almost pure phosphorescence, whereas strong cyan photoluminescence and weak green phosphorescence were observed upon exposure to 360 nm excitation light. Experiment analysis and theoretical calculations demonstrate that the regulation of luminescent color is attributed to the different transition process of excitons from singlet excited states (S1 and S2) to triplet excited states (T1) under various excitation wavelengths. The materials still can maintain the crystalline state under various extreme conditions (ground, recrystallization, high pressure), thereby maintaining the ORTP properties. In addition, the ORTP properties of the materials are very stable to water/heat/light/air. Taking advantage of the multiple luminescence colors, excellent crystallinity and stability, these phosphors can be developed as an advanced anti-counterfeiting ink for printing and hand-painting on a wide range of media, showing an extremely ideal application prospect.
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