X射线光电子能谱
腐蚀
材料科学
扫描电子显微镜
介电谱
点蚀
铝
冶金
氧化物
大气(单位)
能量色散X射线光谱学
电化学
化学工程
分析化学(期刊)
复合材料
电极
化学
环境化学
物理
热力学
工程类
物理化学
作者
Can Peng,Yu-wei LIU,Mingxiao Guo,Tianzhen Gu,Chuan Wang,Zhen-yao WANG,Cheng Sun
标识
DOI:10.1016/s1003-6326(22)65806-0
摘要
The corrosion and pitting behavior of pure aluminum 1060 exposed to Nansha Islands marine atmosphere for 34 months was investigated based on mass loss measurement, scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), and electrochemical impedance spectroscopy (EIS). The results indicated that serious pitting corrosion occurred on the surfaces of pure aluminum. The corrosion rate after exposure for 13 months was approximately 1.28 g/(m2·a). The XPS results showed that the corrosion products were Al2O3, Al(OH)3, and AlCl3. Moreover, the corrosion product layer was more protective than the native oxide film, and the protectiveness first increased and then decreased. Finally, the shape of the pits was evaluated using statistical analysis.
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