纳米团簇
方解石
氢溢流
催化作用
沸石
氢
化学
钯
乙烯
乙炔
光化学
材料科学
无机化学
选择性
有机化学
作者
Shuai Wang,Zhi‐Jian Zhao,Xin Chang,Jiubing Zhao,Hao Tian,Chengsheng Yang,Mingrun Li,Qiang Fu,Rentao Mu,Jinlong Gong
标识
DOI:10.1002/anie.201903827
摘要
Abstract The search for efficient nontoxic catalysts able to perform industrial hydrogenations is a topic of interest, with relevance to many catalytic processes. Herein, we describe a mechanistic phenomenon for the activation and spillover of hydrogen for remarkable selectivity in the semi‐hydrogenation of acetylene over sub‐1 nm Pd nanoclusters confined within sodalite (SOD) zeolite (Pd@SOD). Specifically, hydrogen is dissociated on the Pd nanoclusters to form hydrogen species (i.e., hydrogen atoms and hydroxyl groups) that spill over the SOD surfaces. The design and utilization of the small‐pore zeolite SOD (six‐membered rings with 0.28×0.28 nm channels) is crucial as it only allows H 2 diffusion into the channels to reach the encapsulated Pd nanoclusters and thus avoids over‐hydrogenation to form ethane. Pd@SOD exhibits an ethylene selectivity of over 94.5 %, while that of conventional Pd/SOD is approximately 21.5 %.
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