Micro-hydroxyapatite reinforced Ti-based composite with tailored characteristics to minimize stress-shielding impact in bio-implant applications

Biomaterials having higher strength and increased bioactivity are widely researched topics in the area of scaffold and implant fabrication. Metal-based biomaterials are favorably suitable for load-bearing implants due to their outstanding mechanical and structural properties. The issue with pure metallic material used for bio-implant is the mismatch between the mechanical properties of the human body parts and the implant. The mismatch in modulus and hardness values causes damage to muscles and other body parts due to the phenomena of ‘stress-shielding’. As per the rule of mixture, combining a biocompatible ceramic with metals will not only lower the overall mechanical strength, but will also enhance the composite's bioactivity. In the present work, a Metal-Ceramic composite of Ti and μ-HAp is processed through high-energy mechanical alloying. The μ-HAp powders (in a weight fraction of 1%, 2%, and 3%) were alloyed with Pure Ti powder sintered using microwave hybrid heating (MHH). The homogeneously alloyed materials were inspected for chemical and elemental characteristics using XRD, SEM-EDX, and FTIR analyses. Nano-mechanical and micro-hardness properties were inspected for the fabricated Ti- μ-HAp composites and it shows a decreasing trend. Elastic modulus declined from 130.8 GPa to 50.11 GPa for 3 wt% μ-HAp compared to pure-Ti sample. The mechanical behaviour of developed composites confirms that it can minimize the stress-shielding impact due to comparatively lesser strength and hardness than pure metallic samples.