二苯并噻吩
异质结
烟气脱硫
煅烧
纳米颗粒
催化作用
介孔材料
二硫化钼
钼
复合数
硫黄
纳米技术
化学工程
色散(光学)
光催化
离子液体
化学
材料科学
电子转移
光化学
有机化学
复合材料
光电子学
工程类
冶金
物理
光学
作者
Chenchao Hu,Suhang Xun,Bo Yang,Linhua Zhu,Minqiang He,Mingqing Hua,Mengxia Ji,Wenshuai Zhu
标识
DOI:10.1016/j.seppur.2024.126789
摘要
The well dispersion of active sites and electronic transfer capability frequently determines the catalytic performance, and the rational design of these elements still remains a huge challenge. Herein, MoO3 nanoparticle is obtained by molybdenum based ionic liquid precursor to attain well dispersion, and then load on the few layers g-C3N4 carrier to achieve MoO3/g-C3N4 heterojunction. By controlling the calcination temperature, the layer of g-C3N4 is reduced while obtaining MoO3 nanoparticles under 400 ℃, effectively promoting electron transfer. Characterization results indicate that the successful composite between MoO3 and g-C3N4 and the prepared catalyst shows outstanding desulfurization performance for dibenzothiophene (DBT), achieving 100 % sulfur removal rate within 100 min. The MoO3/g-C3N4 also displays outstanding sulfur removal for 4-methyldibenzothiophene (4-MDBT) (100 %) and 4,6-dimethyldibenzothiophene (4,6-DMDBT) (100 %) due to the significant mesoporous structure. Furthermore, •O2− is confirmed as the main free radical in the oxidative desulfurization system and the possible oxidative desulfurization mechanism is proposed.
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