Abundant Exterior/Interior Active Sites Enable Three-Dimensional PdPtBiTe Dumbbells C–C Cleavage Electrocatalysts for Actual Alcohol Fuel Cells

Developing high-activity electrocatalysts is of great significance for the commercialization of direct alcohol fuel cells (DAFCs), but it still faces challenges. Herein, three-dimensional (3D) porous PdPtBiTe dumbbells (DBs) were successfully fabricated via the visible photoassisted method. The alloying effect, defect-rich surface/interface and nanoscale cavity, and open pores make the 3D PdPtBiTe DBs a comprehensive and remarkable electrocatalyst for the C1-C3 alcohol (ethanol, ethylene glycol, glycerol, and methanol) oxidation reaction (EOR, EGOR, GOR, and MOR, respectively) in an alkaline electrolyte, and the results of in situ Fourier transform infrared spectra revealed a superior C-C bond cleavage ability. The 3D PdPtBiTe DBs exhibit ultrahigh EOR, EGOR, GOR, and MOR mass activities of 25.4, 23.2, 16.8, and 18.3 A mg_{Pd + Pt}^-1, respectively, considerably surpassing those of the commercial Pt/C and Pd/C. Moreover, the mass peak power densities of 3D PdPtBiTe DBs in actual ethanol, ethylene glycol, glycerol, or methanol fuel cells increase to 409.5, 501.5, 558.0, or 601.3 mW mg_{Pd + Pt}^-1 in O₂, respectively. This study provides a new class of multimetallic nanomaterials as state-of-the-art multifunctional anode electrocatalysts for actual DAFCs.