差示扫描量热法
扩展器
材料科学
凝胶渗透色谱法
挤压
环氧树脂
傅里叶变换红外光谱
高分子化学
化学工程
聚乳酸
熔体流动指数
结晶度
高分子
聚合物
复合材料
聚氨酯
共聚物
化学
生物化学
物理
工程类
热力学
作者
Dejun Hao,Congshan Zhu,Zhongyong Fan
摘要
Abstract A novel macromolecular epoxy chain extender was synthesized and used to modify the PLA resin for developing conventional melt extrusion technology. Fourier‐transform infrared spectroscopy (FTIR), gel permeation chromatography (GPC), and 1 H nuclear magnetic resonance ( 1 H NMR) characterized the successful synthesis. For the first time, the molecular weight plays a key role in preventing thermal degradation and chain extension were discussed experimentally. Macromolecular chain extender showed superior advantages in that the chain extender with higher molecular weight was easier to get the long chain branched (LCB) structure in the modification of PLA. The characterization by rotational rheometer, GPC, melt index, chemical titration, and differential scanning calorimeter (DSC), results demonstrate that the macromolecular epoxy chain extender could decrease the concentration of terminal carboxyl groups and increase with only 0.5% dosage. At a concentration ≥2%, there were a large number of long chain branched structures in the chain extension system for modified PLA. It showed better melt strength and would influence the crystallinity of PLA which would significantly improve the processability of PLA, especially in high‐temperature extrusion, blow molding, spinning, and other processing technologies and applications.
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