Novel Green Hydrogen – Fossil Fuel Dehydrogenation

Climate change requires an immediate transition from fossil fuels to clean energy sources. Although hydrogen is considered a future energy source, over 90% of hydrogen is currently produced from fossil fuels, and large-scale renewable-fed hydrogen processes are limited by current technologies and economic processes. Therefore, hydrogen production from fossil fuels is a significant topic, particularly if fossil fuel-fed hydrogen production and utilization can be absolutely carbon-free. For the first time, this review critically discusses and analyzes the current advances and fundamentals of fossil fuel dehydrogenation from the perspective of techno-economic-environmental assessments while considering all potential fossil resources and hydrogen technology. This review concludes that the preference of fossil fuels for any hydrogen production technology is as follows: fossil gas > heavy fossil liquid > light fossil liquid > fossil minerals. Thermo-catalytic hydrocarbon decomposition can outperform most other hydrocarbon reforming and pyrolysis processes owing to its energy efficiency, economic effectiveness, and environmental friendliness. Further, we explore potentially new "green hydrogen" technology and confirm that fossil fuels could be completely decarbonized throughout the full-chain stages from exploration to production and consumption. Overall, this work reveals that fossil fuels can be utilized completely carbon-free and provides technical support for future fossil fuel dehydrogenation and energy decarbonization in academic research, industrial practice, and governmental strategies.