Thermo-Chemical and Dielectric Properties of Bio-based and Eco-friendly Natural Ester Fluids: Power Equipment Applications

矿物油 材料科学 石油 变压器油 变压器 电介质 热的 电绝缘纸 背景(考古学) 天然气 环境科学 热导率 废物管理 石油工程 可再生能源 工艺工程 化石燃料 植物油 石油产品 红外光谱学 自然(考古学) 介电强度 耗散因子 质谱法 热分析
作者
Dhorali Gnanasekaran,Venkata Prasad Chavidi
出处
期刊:IEEE Transactions on Dielectrics and Electrical Insulation [Institute of Electrical and Electronics Engineers]
卷期号:: 1-1
标识
DOI:10.1109/tdei.2025.3619456
摘要

Increasing environmental concerns and depleting petroleum reserves are driving explorations for renewable and biodegradable insulating fluids for transformer applications. Conventional mineral oils face disposal challenges, prompting search for alternatives. Vegetable oil-based transformer fluids meet many of these needs. To address the above issue, one of our recent studies explored a non-edible vegetable oil-based natural ester, an eco-friendly and fire-resistant insulating fluid for application in transformers. This study analyses chemical properties of natural esters using various techniques, viz., Fourier-transform infrared spectroscopy (FT-IR) and Gas chromatography coupled with mass spectrometry (GC-MS). The natural ester was also examined for thermal properties including thermal conductivity, thermal degradation, and dielectric characteristics. Results were compared with conventional mineral oil in accordance with national and international standards. Our findings show that thermal conductivity of the natural ester studied in this context decreases by 10% as the temperature increases from 25 to 100 °C. Electrical properties meet the requirements as per IEC 62770 and have been proven to be an excellent alternative to mineral oil. Natural esters provide numerous benefits owing to their cost-effectiveness and environmental sustainability, in addition to being biodegradable and renewable, and do not compete with food industry. Adopting such natural esters as alternative insulating fluids in electrical equipment would lead to a greener future in transformer applications.
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