材料科学
阳极
聚丙烯腈
合金
无定形碳
化学工程
阴极
电极
无定形固体
复合材料
碱金属
纳米技术
化学
聚合物
结晶学
有机化学
物理化学
工程类
作者
Shujuan Meng,Ningxiang Wu,YangQuan Chen,Xu Han,Yu Shen,Weina Zhang,Bing Zheng,Sheng Li,Fengwei Huo
标识
DOI:10.1016/j.cclet.2022.107767
摘要
Compared with solid alkali metal anodes (Li, Na, K), liquid metal anodes (LMAs) could enable high-energy batteries due to their unique advantages, such as self-healing property and no dendrites. Among LMAs, liquid Na-K alloy anode has become a hotspot due to its high theoretical capacity, low redox potential and formation at room temperature (RT). However, it is challenging to utilize liquid Na-K alloy directly and independently as an electrode; and the high surface tension makes it more difficult to immerse into porous current collectors at RT. Herein, an amorphous hollow carbon film (AHCF) consisting of hollow spheres with significant surface defects has been designed to quickly infiltrate Na-K liquid alloy into the hollow carbon film at RT, forming a composite electrode (Na-K@AHCF). The symmetric cell with Na-K@AHCF could exhibit a cycle lifespan up to 400 h at 0.1 mA/cm2 and achieve stable stripping/deposition even at 5 mA/cm2. When matching with cathode material of sulfurized polyacrylonitrile (SPAN), the obtained K-S full cell exhibits good cycle stability and rate performance.
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