Microstructure and Superplastic Behavior of Ni-Modified Ti-Al-Mo-V Alloys

The paper studies the influence of 0.5–1.8 wt.% Ni alloying on the superplasticity, microstructural evolution, and dynamic grain growth effect in a temperature range of 625–775 °C and room temperature mechanical properties of two-phase Ti-Al-Mo-V alloys. Due to a decrease in β transus and an enhancement in the alloy diffusivity, an increase in Ni content significantly improved superplasticity. The Ni-modified alloys exhibited 1.5–3-fold lower flow stress, a 2.5–3-fold greater elongation to failure, and 1.4–1.7-fold higher strain rate sensitivity m coefficient compared to the Ni-free alloy. An intermetallic Ti2Ni compound precipitated in the 1.8 wt.% Ni-modified alloy during low-temperature deformation at 700 °C and decreased superplastic properties. The Ti-4Al-3Mo-1V-0.1B alloy with 0.9 wt.% Ni exhibited a good combination of the superplastic behavior and room-temperature mechanical properties: an elongation to failure of 500–900% at a low-temperature range of 625–775 °C and constant strain rate of 1 × 10−3 s−1 and a yield strength of 885 MPa and ultimate tensile strength of 1020 MPa after pre-straining for 100% in a superplastic regime and strengthening heat treatment.