区域选择性
硼烷
试剂
基质(水族馆)
化学
硼
过渡金属
分子
可见光谱
组合化学
光催化
光化学
有机化学
催化作用
材料科学
海洋学
光电子学
地质学
作者
Xinghua Liu,Yujing Shen,Cheng Lu,Yongchan Jian,Shuangshuang Xia,Zhaoliang Gao,Yi-Han Zheng,Yuanyuan An,Yubin Wang
摘要
A photo-induced transition-metal-free regioselective hydroborylation of α,β-unsaturated carbonyl compounds is developed. The PhSSPh reagent was employed as the photocatalyst, and NHC-BH3 was used as the boron source. This transformation shows a broad substrate scope and provides a wide range of α-borylcarbonyl molecules in good to excellent yields.
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