Hydroxylamine, Oximate and Hydroxamate as α‐Nucleophiles in Dephosphorylation

This chapter contains sections titled: Introduction THE α-Effect of Hydroxylamines, Oximes and Hydroxamic Acids Ambident Nature of Hydroxylamines and Hydroxamates Leveling Effect of α-Nucleophilicity: Brønsted-Type Plots Solvent Effect on α-Nucleophilicity Acetonitrile–Water Versus DMSO–Water Binary Mixtures Imbalanced Transition State Hydroxylamines, Hydroxamates and Oximates as Antidotes for Intoxications by Organophosphorus Toxins (Chemical Warfare Agents) and Organophosphorus Insecticides Reactions of Oximate and Hydroxamate Nucleophiles in Surfactant Systems Acknowledgment References