化学
三氟甲基
光催化
催化作用
光催化
烷基
光化学
联轴节(管道)
有机化学
组合化学
机械工程
工程类
作者
Yasuyo Tahara,Koushik Ghosh,Masakazu Nambo
标识
DOI:10.1139/cjc-2022-0271
摘要
The synthesis of gem-difluoroalkenes by photocatalytic desulfonylative coupling of alkylsulfones with α-(trifluoromethyl)styrenes is described. Photoredox Ir complex was found to be an effective catalyst for this transformation through single electron reduction of alkyl 1-phenyltetrazolyl sulfones, providing structurally diverse gem-difluoroalkene products in good yields. The resulting alkenes could be further converted into fluorinated derivatives, highlighting the potential utility of this method in the synthesis of organofluorine compounds.
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