Selective capture of palladium from acid wastewater by thiazole-modified activated carbon: Performance and mechanism

As a kind of scarce metal, palladium is widely used in many chemical industries. It essential to recover palladium from secondary resources, especially acidic media, owing to high content of palladium in secondary wastes and widespread extraction of palladium via strong acids. Chemically modified carbon materials not only have the advantage of activated carbon but also achieve the precise removal of specific pollutants, which is a kind of adsorption material with broad application prospects. In this direction, we report a solid carbon material named AT-C, which is obtained by one-step synthesis of 2-aminothiazoles grafted to the carbon surface by amidation. The present adsorbent delivers a high palladium adsorption capacity of 178.9 mg g-1, and desirable thermal and chemical stability. The uniform presence of abundant sulfur atoms and CO in the porous network enables AT-C to achieve selective absorption and rapid adsorption kinetics of Pd2+ in the complex water mixture containing many competing ions in the acidic pH range. For the strongly acidic leachates of catalysts, AT-C exhibits outstanding stability in cyclic experiments. Meanwhile, the fixed-bed column test indicates that 1076 bed volumes of the feeding streams can be effectively treated. In addition, AT-C exhibits superior adsorption selectivity, and the recovery efficiency of Pd2+ in actual industrial wastewater is 96.6%. This work realizes an efficient, rapid, and selective removal of palladium under acidic conditions, and provides a reference for complex industrial water treatment and resource recovery of precious metals.