Pt–Cu@Bi2MoO6/TiO2 Photocatalyst for CO2 Reduction

Bi2MoO6/TiO2 heterojunction photocatalysts were constructed by depositing Bi2MoO6 nanosheets on TiO2 nanobelts’ surface using a solvothermal method, and the surface of the optimum Bi2MoO6/TiO2 composite was decorated with copper and/or platinum nanoparticles. The synthesized samples were investigated for the CO2 photocatalytic reduction. The structural and optical properties of synthesized photocatalysts were characterized by XRD, FESEM, EDX, N2-physisorption, Raman, TPD-CO2, DRS, and PL analysis. The Bi2MoO6/TiO2 composite with different molar ratios of Bi2MoO6 to TiO2 (1, 1/2, 1/3, 1/4, 1/5, and 1/6) showed enhanced photocatalytic activity compared to pure Bi2MoO6 and TiO2. In comparison to bulk Bi2MoO6 and TiO2, the formation of a heterojunction between Bi2MoO6 and TiO2 leads to enhanced CO2 adsorption capacity. The enhanced performance of composites can be ascribed to the improved efficiency of light harvesting in the visible light range and suppressing charge recombination. The composite photocatalytic activity indicated that the ratio of Bi2MoO6 to TiO2 in the composite samples influenced the photocatalytic performance. The Bi2MoO6/TiO2 composite with 1/4 molar ratio had the best performance in 8 h (36.4 μmol/gcat), which was about 10 and 3 times higher than TiO2 and Bi2MoO6 photocatalysts, respectively. Under UV–visible light irradiation, the Pt–Cu@BMT4 sample produced the highest amount of methane (83.6 μmol/gcat) during CO2 photoreduction. During four irradiation cycles, the Pt–Cu@BMT4 sample exhibited superior stability with less than 5% decrease in methane production.