异丁烯
甲基丙烯酸
选择性
氧气
化学
催化作用
产量(工程)
无机化学
有机化学
材料科学
聚合
共聚物
聚合物
冶金
作者
Xu Liu,Qingrong Wang,Ziqi Zhou,Ming Bao,Jiasheng Wang
摘要
Efficient one-step oxidation of isobutylene to methacrylic acid was achieved over a Mo-V-Te-Cs catalyst. Mo-O-V as "asymmetric lattice oxygen" brings high activity. Te and Cs provide a suitable medium acidity to enhance the selectivity. A record single-step yield of 65% for methacrylic acid was obtained from isobutylene oxidation.
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