Effect of silver nanoparticles on the photostability and aging of CsPbBr3 nanocrystals

Abstract Perovskite nanocrystals may become a promising replacement for current phosphors in light-emitting diodes (LEDs) and screens, but the question of the stability of their optical properties remains open. One way to solve this problem could be to use plasmonic nanoparticles. In this work, we investigate the combination of all-inorganic perovskite nanocrystals synthesized by the hot-injection method with spherical Ag nanoparticles (mean diameter 53 nm). 3-fold enhancement of photoluminescence (PL) has been implemented in hybrid ‘silver-CsPbBr 3 -polymethyl methacrylate’ structures. The presence of silver nanoparticles reduces the likelihood of Auger processes and forms a possible silver bromide barrier layer which prevents photoinduced ion migration in the perovskite-polymer film. Plasmonic enhancement of PL partially presents during long-term samples storage within 75 days. This work may be useful in the creation of perovskite LEDs using remote phosphor technology.