化学
催化作用
钴
酒精氧化
同种类的
多相催化
氧气
热解
分子氧
有机化学
碳纤维
氮气
氧化磷酸化
复合材料
材料科学
物理
复合数
热力学
生物化学
作者
Rajenahally V. Jagadeesh,Henrik Junge,Marga‐Martina Pohl,Jörg Radnik,Angelika Brückner,Matthias Beller
摘要
Novel cobalt-based heterogeneous catalysts have been developed for the direct oxidative esterification of alcohols using molecular oxygen as benign oxidant. Pyrolysis of nitrogen-ligated cobalt(II) acetate supported on commercial carbon transforms typical homogeneous complexes to highly active and selective heterogeneous Co3O4–N@C materials. By applying these catalysts in the presence of oxygen, the cross and self-esterification of alcohols to esters proceeds in good to excellent yields.
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