Luminescent cyanide coordination polymer based on {Mo6I8} and {Ag2(dppm)2} clusters: exceptional stability and efficient scintillation

First metal-organic coordination polymer based on [{Mo6I8}(CN)6]2– cluster anion was obtained using salts Cs1.3Na0.7[{Mo6I8}(CN)6]·2H2O (1) and K[Ag(CN)2], as well as bis(diphenylphosphino)methane (dppm) as precursors. In contrast to the previously reported...