Composites from Recycled Polypropylene and Carboxymethylcellulose with Potential Uses in the Interior Design of Vehicles

材料科学 复合材料 复合数 聚丙烯 羧甲基纤维素 傅里叶变换红外光谱 热稳定性 造型(装饰) 维氏硬度试验 微观结构 化学工程 工程类 冶金
作者
Alina Ruxandra Caramitu,Romeo Cristian Ciobanu,Ioana Ion,Mihai Marin,Eduard-Marius Lungulescu,Virgil Marinescu,Magdalena Aflori,Adriana Mariana Borș
出处
期刊:Polymers [Multidisciplinary Digital Publishing Institute]
卷期号:16 (15): 2188-2188 被引量:4
标识
DOI:10.3390/polym16152188
摘要

This research investigates novel polymeric composite materials for automotive interior trim applications. The composites utilize recycled polypropylene (PPr) matrix and carboxymethylcellulose (CMC) as filler (PPr/CMC: 100/0, 95/5, and 90/10 wt.%). The materials were processed by extrusion and injection molding. Considering their intended application, the composites were evaluated for resistance to key climatic factors, i.e., temperature, humidity, and UV radiation. In addition, structural analyses and FTIR analyses were performed to assess potential heterogeneity and thermal stability. Following FTIR tests, the incorporation of carboxymethyl cellulose in polypropylene is confirmed by the detection of characteristic CMC bands for -OH, C=O, and C-O-C groups. The results indicate slight structural heterogeneity in the 5% and 10% CMC composites. However, no thermal distortions were observed in either the composites or the PPr matrix itself. The behavior of PPr/CMC composites under the action of the mentioned climatic factors has been assessed from the variation of dielectric characteristics with frequency. The strong polarization of CMC leads to a sharp increase in composites electrical conductivity after submersion in water for 480 h, suggesting weakening of the composite structure. After exposure to UV radiation, a sharp increase in conductivity is observed even after the first cycle (72 h) of UV radiation. Following the experimental results obtained in our study, it is recommended to use the PPr +10% CMC composite for obtaining different interior ornaments (carpets, supports, etc.). At the same time, the use of these materials also has the advantage of lightening the mass of the vehicle due to their lower density than polymers.
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