化学
表面改性
联轴节(管道)
组合化学
Atom(片上系统)
原子经济
催化作用
有机化学
并行计算
计算机科学
机械工程
工程类
物理化学
作者
Yaohong Zhang,Mengqiang Luo,Yichan Zhang,Kai Cheng,Yong Li,Chenze Qi,Runfu Shen,Hai Wang
摘要
A facile and efficient oxidative functionalization of vinyl azides with aldehydes furnishing a diverse array of β-acylated enaminones was developed. The cross coupling was accomplished in the presence of CuCl2·2H2O/TBHP and produced the desired β-acylated enaminones in a (Z)-stereo-selective and atom-economic manner, which make this protocol particularly attractive. In the transformation, the new C-C and C-N bonds were formed via a one-pot strategy including the process of radical addition and recombination.
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