异质结
可见光谱
光催化
双金属片
降级(电信)
催化作用
化学
复合数
氧化物
材料科学
光化学
化学工程
核化学
光电子学
有机化学
计算机科学
复合材料
电信
工程类
作者
Chunhui Shen,Cheng-Gang Niu,Zhenghao Fei,Zongtang Liu,Qi-Ming Mu
标识
DOI:10.1016/j.cej.2019.123612
摘要
The development of simple and effective approaches for the synthesis of bimetallic oxide heterojunction photocatalyst which are used to activate peroxymonosulfate (PMS) under visible-light-driven is highly feasible but remains a great challenge. In this work, the Co3O4/CeO2 composite was prepared by a facile chemical reaction, followed by annealing in a muffle furnace and then applied to activate PMS for ciprofloxacin (CIP) degradation. Various characterizations confirmed the formation of p-n heterojunction between Co3O4 and CeO2. Meanwhile, the 5 wt% Co3O4/CeO2/PMS composite showed highest degradation rate of CIP (87.8%) under visible light irradiation. The obtained Co3O4/CeO2/PMS system still exhibited a good catalytic performance in presence of different anion. Besides, the active radical h+, OH, O2−, and SO4− are involved in CIP degradation. The excellent degradation performance can be interpreted as the synergistic effect between Co3O4/CeO2 heterojunction photocatalyst and PMS activation. Moreover, the energy band structure and valence band deviation of Co3O4/CeO2 p-n heterogeneous junction were confirmed. This work would give a reference for combining the photocatalyst and activation of PMS under visible light for further removal of pollutants.
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