Superior thermally robust energetic materials featuring Z–E isomeric bis(3,4-diamino-1,2,4-triazol-5-yl)-1H-pyrazole: self-assembly nitrogen-rich tubes and templates with Hofmeister anion capture architecture

A super thermally robust nitrogen-rich framework was synthesized, and Z → E isomerization as well as supramolecular assembly inclusion strategy gave rise to two different nitrogen-rich tubes and templates with Hofmeister anions capture architecture.