化学
双金属片
检出限
纳米材料
纳米颗粒
电子转移
催化作用
碳纳米管
适体
过氧化物酶
葡萄糖氧化酶
线性范围
化学工程
纳米技术
金属有机骨架
电极
光化学
酶
物理化学
材料科学
有机化学
色谱法
吸附
工程类
生物
遗传学
作者
Xueming Dang,Huimin Zhao
出处
期刊:Talanta
[Elsevier]
日期:2020-04-01
卷期号:210: 120678-120678
被引量:45
标识
DOI:10.1016/j.talanta.2019.120678
摘要
A hybrid of metal-organic frameworks (Fe, Mn) and Au nanoparticles anchored carbon nanotubes (Au/MOFs(Fe, Mn)/CNTs) was fabricated by a facile one-step hydrothermal process. The Au/MOFs(Fe, Mn)/CNTs exhibit highly enhanced peroxidase-like activity, because of the increased active sites, the enhanced partial charge density and electron transfer among the Fermi level of MOFs, Au and CNTs, as well as the synergistic action of Fe and Mn. The hybrid nanomaterials with high catalytic velocity (Vmax = 17.65 × 10-7 M s-1) and affinity (Km = 0.33 mM) for substrates of H2O2 display a great detection performance in the range of 0.34-53.05 nM with a limit of detection (LOD) of 0.18 nM (S/N = 3). Based on the cascade reaction of the artificial peroxidase and glucose oxidase (GOx), the glucose was further better detected in a linear range of 0.005-0.3 μM with a LOD of 0.002 μM (S/N = 3). Notably, considering the regulated peroxidase-like activity by sulfadimethoxine (SDM) aptamer, the concentration of SDM ranging from 0.54 to 41.58 μg L-1 was also detected with a LOD of 0.35 μg L-1 (S/N = 3). The as-synthesized hybrid nanozymes hold promising applications as the multifunctional sensing platform in environmental and biologic target detection with the combination of corresponding enzyme or specific aptamer.
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