Facile Fabrication of Room-Temperature Self-Healing, Mechanically Robust, Highly Stretchable, and Tough Polymers Using Dual Dynamic Cross-Linked Polymer Complexes

The development of polymeric materials with a combination of excellent mechanical performance and room-temperature self-healing property is still a huge challenge. Here, we report a facile method for the fabrication of dual dynamic cross-linked polymer complexes that simultaneously possess multiple remarkable mechanical properties and room-temperature self-healability by simply mixing polymers that have complementary interactions in solutions. Thanks to the synergistic effects of electrostatic and hydrogen-bonding interactions within their networks, the complexes obtained a superhigh tensile strength of 27.4 MPa and toughness of 110.0 MJ/m³ when compared with other polymers that can self-heal at room temperature. More importantly, the complexes can repair a physical cut in an ∼90% relative humid environment at room temperature with a high healing efficiency of ∼96% because of the dynamic nature of the noncovalent interactions. This method is a simple, low-cost, and widely applicable strategy for the large-scale fabrication of room-temperature self-healing materials that possess superior and controllable mechanical performances.