Influence of SiO2 nanoparticles on electro-optical and thermophysical properties of polyacrylate/liquid crystal composites

In this paper, SiO2 nanoparticle-doped polymer dispersed liquid crystal (PDLC) lenses are made from a mixture of prepolymer, 5CB liquid crystal and SiO2 nanoparticles by the polymerisation induced phase separation (PIPS) process. The effect of SiO2 nanoparticles on the electro-optical properties of PDLC films are studied. It is established that SiO2 nanoparticles affect the microstructure of PDLC films significantly because of the formed agglomerates of SiO2 nanoparticles. Results show an improvement in the electro-optical properties and a decrease in the response time for doped systems with small amount of SiO2 nanoparticles. We also observe a shift of nematic–isotropic transition temperature as a function of SiO2 nanoparticle contents. A good agreement between the electro-optical study and thermophysical properties is reached.