Hydrothermal carbonization of various lignocellulosics: Fuel characteristics of hydrochars and surface characteristics of activated hydrochars

In the present study, various lignocellulosic biowastes (wood sawdust, olive pomace, walnut shell, apricot seed, tea stalk, hazelnut husk) were hydrothermally carbonized at 220 °C for 90 min. Since the hydrochars have several end-uses, this study particularly investigates their end-use as solid fuels and precursors of activated carbon after chemical activation. Activated hydrochars were obtained from the hydrochars of wood sawdust, olive pomace, walnut shell, apricot seed, tea stalk, hazelnut husk by chemical activation with KOH at 600 °C. As fuels, all hydrochars had higher fixed carbon content, lower volatile matter content and higher ignition temperatures compared to their original biomass samples. Olive pomace hydrochar, which has high heating value (25.56 MJ/kg) and low ash content (5.5%), has the best fuel properties among hydrochars investigated. Activated hydrochars demonstrated BET surface areas of 308.9-666.7 m2/g (activated hydrochar of wood sawdust and tea stalk), and total pore volumes of 0.25-0.73 cm3/g (activated hydrochar of olive pomace and wood sawdust). The average pore size distribution of the activated hydrochars ranged between 1.05 nm (olive pomace)- 4.74 nm (wood sawdust). All agricultural-based activated hydrochars had similar average pore size distribution of 1.05-1.25 nm, which fell in the range of super-microporous structure. With the average pore size of 4.74 nm, activated hydrochar of wood sawdust could be classified under mesoporous structure. This study clearly points out that biomass type definitely affected fuel properties of hydrochars and the porous structure of the activated hydrochars.