Bioinspired Self‐Standing, Self‐Floating 3D Solar Evaporators Breaking the Trade‐Off between Salt Cycle and Heat Localization for Continuous Seawater Desalination

Abstract Facing the global water shortage challenge, solar‐driven desalination is considered a sustainable technology to obtain freshwater from seawater. However, the trade‐off between the salt cycle and heat localization of existing solar evaporators (SE) hinders its further practical applications. Here, inspired by water hyacinth, a self‐standing and self‐floating 3D SE with adiabatic foam particles and aligned water channels is built through a continuous directional freeze‐casting technique. With the help of the heat insulation effect of foam particles and the efficient water transport of aligned water channels, this new SE can cut off the heat transfer from the top photothermal area to the bulk water without affecting the water supply, breaking the long‐standing trade‐off between salt cycle and heat localization of traditional SEs. Additionally, its self‐standing and self‐floating features can reduce human maintenance. Its large exposure height can increase evaporation area and collect environmental energy, breaking the long‐standing limitation of solar‐to‐vapor efficiency of conventional SEs. With the novel structure employed, an evaporation flux of 2.25 kg m −2 h −1 , and apparent solar‐to‐vapor efficiency of 136.7% are achieved under 1 sun illumination. This work demonstrates a new evaporator structure, and also provides a key insight into the structural design of next‐generation salt‐tolerant and high‐efficiency SEs.