多硫化物
溶解
磷酸盐
化学工程
肥料
化学
磁导率
扩散
多孔性
控制释放
材料科学
矿物学
有机化学
电解质
膜
生物化学
物理
电极
物理化学
工程类
热力学
作者
Stella F. Valle,Amanda S. Giroto,Cauê Ribeiro
出处
期刊:ACS applied polymer materials
[American Chemical Society]
日期:2023-08-16
卷期号:5 (9): 6941-6949
标识
DOI:10.1021/acsapm.3c00988
摘要
Phosphate rock and struvite (ST) dispersion in a polysulfide (PS) matrix offers a sustainable alternative for phosphorous (P) fertilization, as it can favor P dissolution and control its release, while also being a sulfur fertilizer. Herein, we discuss the PS permeability mechanism as well as the chemical and structural factors that affect P diffusion from PS composites. SEM and contact angle showed that P particles increased PS porosity and hydrophilicity, which favors P release. Within 7 days in soil, Fe-oxide papers revealed that the P-diffusion diameter was only 0.3 cm for ST against up to 2.3 cm from the PS composite. In 28 days, available P in soil from the apatite increased from 6 to up to 79 mg/dm3 due to its dispersion in PS. In the adapted Ussing Chamber permeability test, PS displayed higher affinity toward anion permeability and a negligible cation diffusion, which might contribute to the gradual P release and higher availability in soil.
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