荧光粉
显色指数
发光
固态照明
激活剂(遗传学)
色温
兴奋剂
离子
发射强度
二极管
分析化学(期刊)
化学
材料科学
光电子学
发光二极管
生物化学
基因
有机化学
色谱法
作者
Min Liao,Fugen Wu,Daoyun Zhu,Xin Zhang,Huafeng Dong,Zhiping Lin,Minru Wen,Zhongfei Mu
标识
DOI:10.1016/j.cej.2022.137801
摘要
Phosphors with single broadband white emission are ideal for solid-state lighting applications. However, achieving single broadband white emission in a single activator doped single component phosphor is very challenging. Herein, by introducing a small amount of Cl- ions into the Rb0.5K1.5Ca0.995PO4F: 0.5%Eu2+ phosphor, we effectively controlled the selective occupation of Eu2+ ions at Ca sites or K/Rb sites and obtained a single broadband white emission phosphor Rb0.5K1.5Ca0.995PO4F0.8Cl0.2: 0.5%Eu2+. The luminescence of this phosphor presents a desirable full width at half maximum (274 nm) and excellent thermal stability (81.9%@150 °C of the integrated emission intensity at room temperature). A white light-emitting diode with high color rendering index (Ra = 93.6) and suitable correlated color temperature (4163 K) was successfully fabricated using Rb0.5K1.5Ca0.995PO4F0.8Cl0.2: 0.5%Eu2+ phosphor and a 365 nm chip, demonstrating the significant application value of as-prepared phosphors in the field of solid-state lighting. This work provides an effective design strategy for the development of single activator doped single component white light emitting phosphors, which will facilitate the development of related phosphors in the future.
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