光催化
异质结
材料科学
化学工程
降级(电信)
电子受体
退火(玻璃)
接受者
热分解
纳米技术
催化作用
光化学
化学
光电子学
复合材料
工程类
有机化学
物理
电信
生物化学
计算机科学
凝聚态物理
作者
Qian Liang,Wen Gao,Changhai Liu,Song Xu,Zhongyu Li
标识
DOI:10.1016/j.jhazmat.2020.122500
摘要
1D spindle-like iron oxides with controllable phase were synthesized by using MIL-88A-templated pyrolysis under different atmospheres, thermal annealing in N2 to obtain Fe3O4 and in air to obtain α-Fe2O3. Then, 2D/1D core-shell heterostructures (ZnIn2S4@Fe3O4 and ZnIn2S4@α-Fe2O3) were constructed by in-situ self-assembly strategy. Characterizations indicated that the 2D ultra-thin ZnIn2S4 shell with 0.3 μm was homogeneously coated on the surface of 1D Fe3O4/α-Fe2O3 core with 1 μm, and ZnIn2S4@Fe3O4 exhibited higher BET surface area (84.5 m2 g−1) compared with ZnIn2S4@α-Fe2O3 (17.8 m2 g−1), providing more exposed active sites and larger contact area. The ZnIn2S4@Fe3O4-5 showed the best photocatalytic activity of RhB degradation as compared to ZnIn2S4, Fe3O4 and ZnIn2S4@α-Fe2O3. In addition, the degradation rates of MB, BPA and MO over ZnIn2S4@Fe3O4 were much higher than that of ZnIn2S4@α-Fe2O3. The proposed photocatalytic mechanism was also discussed: the Fe3O4 as an electron acceptor caused Fe3+/Fe2+ cycle in ZnIn2S4@Fe3O4 and ZnIn2S4@α-Fe2O3 followed the Z-scheme mechanism.
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