Towards maximizing the In2O3/m-ZrO2 interfaces for CO2-to-methanol hydrogenation

Through chelating-assisted impregnation with diethylenetriamine-pentaacetic acid (DTPA), we developed an efficient and durable CO2 hydrogenation catalyst, In15/m-ZrO2-DTPA, featuring improved In2O3 reducibility and interfacial Zr-O-In structures. Benefiting from its distinct CO2 activation and hydrogenation ability, In15/m-ZrO2-DTPA exhibited remarkable CO2-to-methanol catalytic activity, achieving up to 91% selectivity at 260 °C and 5.0 MPa, with consistent conversion maintained over 400 hours.