材料科学
带隙
黄铜矿
镧
扫描电子显微镜
锰
镁
分析化学(期刊)
纳米颗粒
透射电子显微镜
兴奋剂
铜
光谱学
无机化学
纳米技术
化学
冶金
光电子学
复合材料
物理
量子力学
色谱法
作者
Maribel Guzman,Wei Tian,Chantal Walker,Jose E. Herrera
摘要
Copper oxide (Cu 2 O) is a promising semiconductor for photovoltaic and photocatalytic applications since this material has a high optical absorption coefficient and lower band gap (2.17 eV). Doped lanthanum (La), magnesium (Mg) and manganese (Mn) Cu 2 O nanoparticles (Cu 2 O Nps) were prepared by a displacement reaction. The doped and undoped Cu 2 O Nps were characterized with scanning electron microscopy–energy dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD), transmission electron microscopy (TEM) and ultraviolet–visible spectroscopy. The EDS results confirm the presence of La, Mg and Mn in the Cu 2 O Nps. The XRD results confirm the formation a single cubic phase of Cu 2 O with a cuprite structure. TEM images confirm the formation of Nps with mean diameters between 12.0 ± 6.1 and 30.8 ± 11.0 nm. Doped and undoped Nps present a narrow band gap (2.40 eV), blue shifted with respect to bulk Cu 2 O.
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