Recent Advances in Di-tert-butyl Peroxide (DTBP)-Promoted C-C Bond Formation Reactions

Di-<i>tert</i>-butyl peroxide is a commonly used organoperoxide in many oxidation transformations. The primary factors contributing to the increasing usefulness of DTBP include its affordability, eco-friendliness, exceptional efficacy, and capacity to substitute harmful or rare heavy metal oxidants. In this decennial update, we thoroughly examined noteworthy C-C bond formation reactions promoted by DTBP from 2014 till the present. This review centers on the benefits and drawbacks of synthetic organic transformations using DTBP, as well as their extent and underlying mechanisms.