化学
席夫碱
发光
荧光
结合常数
化学计量学
分子内力
检出限
水溶液
光化学
螯合作用
配体(生物化学)
密度泛函理论
物理化学
无机化学
结晶学
立体化学
计算化学
结合位点
色谱法
生物化学
物理
光电子学
量子力学
受体
作者
R. Behura,P. R. Dash,Patitapaban Mohanty,Susanta Kumar Behera,Monalisa Mohanty,Rupam Dinda,Santosh Kumar Behera,Aruna Kumar Barick,Bigyan R. Jali
标识
DOI:10.1016/j.molstruc.2022.133310
摘要
Luminescent chemosensors based on Schiff bases have drawn tremendous research interest owing to their easy synthesis, enriched photophysical properties, and potential applications in biology and materials science. A dinitrophenyl-based Schiff base molecular probe (L) was synthesized and characterized to estimate its selective detection of Zn2+. The probe L exhibits weak emission in the DMSO-H2O solvent mixture due to excited-state intramolecular proton transfer (ESIPT). Interestingly, fluorescence is enhanced with the addition of Zn2+ to the DMSO-H2O solution of L, whereas the emission remains unchanged with the addition of other ions. This specifies that probe L acts as a selective chemosensor for Zn2+. The binding stoichiometry for the L: Zn2+ complex is 1:1, which was calculated using the Benesi-Hildebrand plot from fluorescence data. Furthermore, the binding modes are also supported by density functional theory (DFT) calculation. The binding constant and detection limits are 6.35 × 107 M−1 and 1.1 × 10−8 M, respectively. The L-Zn2+ complex formation is reversible upon the addition of a strong chelating EDTA ligand. In addition, L is also used to detect Zn2+ in living Hela cells and selective sensing of Zn2+ in the solid phase.
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