超级电容器
二硒醚
掺杂剂
材料科学
电化学
钒
兴奋剂
X射线光电子能谱
镍
纳米技术
无机化学
化学工程
化学
电极
光电子学
物理化学
硒
冶金
工程类
作者
Shubra Lalwani,Swapnil S. Karade,Jeong-Hyun Eum,Han Sung Kim
出处
期刊:ACS applied energy materials
[American Chemical Society]
日期:2021-02-22
卷期号:4 (3): 2430-2439
被引量:18
标识
DOI:10.1021/acsaem.0c02953
摘要
Dual doping of the cation–anion in the layered nanomaterials can be an effective strategy to precisely address the chief electrochemical barriers in achieving maximum energy and power for supercapacitor materials. To reap the maximum benefits from the above approach, we synthesized vanadium and sulfur dual-doped nickel diselenide (V, S-NiSe2) nanodiscs on carbon cloth. The X-ray photoelectron spectroscopy results strongly suggested the key role of S as a second dopant in assisting V (with low electronegativity) to alter the electron density around Ni. This shift of electron density from V with the assistance of S facilitated maximum transfer of charge from Ni also promoting rapid redox reactions, which is supported by a 22% increment in b-value (0.62), 89% electro active sites, and 2.4 times swift diffusion of the OH– ions. In addition, V, S-NiSe2 nanodiscs also presented an excellent charge storage of 1464 F g–1@1 A g–1 and a good rate capability of 70% until 20 A g–1, exceeding those of NiSe2 and V-doped NiSe2. In relation, a hybrid supercapacitor cell is also fabricated by assembling the V, S-NiSe2 with an activated carbon electrode, presenting a remarkable energy density of 28.0 W h kg–1 at a power density of 714.7 W kg–1 with reputable cycling stability.
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