六亚甲基二异氰酸酯
异氰酸酯
热重分析
三聚体
傅里叶变换红外光谱
滴定法
缩二脲试验
热稳定性
聚氨酯
高分子化学
材料科学
异佛尔酮二异氰酸酯
核化学
化学
尿素
化学工程
有机化学
复合材料
二聚体
工程类
作者
Ponnusamy Thillai Arasu,Panneer Selvam Seenidurai,Arumugam Murugan,S. Elangovan
出处
期刊:Letters in Applied NanoBioScience
[AMG Transcend Association]
日期:2020-10-03
卷期号:10 (1): 1889-1895
标识
DOI:10.33263/lianbs101.18891895
摘要
An active hydroxyl content of Borassus flabellifer leaf sheath fibers are measured by the isocyanate back titration method, catalytically reacted with 1, 6 – hexamethylene diisocyanate biuret trimer and 2, 4-toluene diisocyanate-trimethylolpropane adduct, which is being used as cross-linkers in most of the automotive and industrial polyurethane coatings. The functional modifications of the fibers are confirmed by NCO titration method and Fourier-transform Infrared Spectroscopy (FTIR). The resultant biochemical fiber is analyzed for the thermal property, and surface topography measurement is done by Scanning Electron Microscope (SEM) and Thermogravimetric analysis (TGA), respectively. Moreover, 1, 6 – hexamethylene diisocyanate biuret trimer (HDT) treated BFSF having higher thermal stability due to higher urethane to urea content and intermolecular hydrogen bonding.
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