Biocatalytic membranes for combating the challenges of membrane fouling and micropollutants in water purification: A review

Over the last few years, the list of water contaminants has grown tremendously due to many anthropogenic activities. Various conventional technologies are available for water and wastewater treatment. However, micropollutants of emerging concern (MEC) are posing a great threat due to their activity at trace concentration and poor removal efficiency by the conventional treatment processes. Advanced technology like membrane technology can remove MEC to some extent. However, issues like the different chemical properties of MEC, selectivity, and fouling of membranes can affect the removal efficiency. Moreover, the concentrate from the membrane filtration may need further treatment. Enzymatic degradation of pollutants and foulants is one of the green approaches for removing various contaminants from the water as well as mitigating membrane fouling. Biocatalytic membranes (BCMs), in which enzymes are immobilized on membranes, combines the advantages of membrane separation and enzymatic degradation. This review article discussed various commonly used enzymes in BCMs for removing MEC and fouling. The majorly used enzymes were oxidoreductases and hydrolases for removing MEC, antifouling, and self-cleaning ability. The various BCM synthesis processes based on entrapment, crosslinking, and binding have been summarized, along with the effects of the addition of the nanoparticles on the performances of the BCMs. The scale-up, commercial viability, challenges, and future direction for improving BCMs have been discussed and shown bright possibilities for these new generation membranes.