SYNTHESIS AND REACTION OF NEW TYPE I–N YLIDE, N-TOSYLIMINOIODINANE

Abstract (Diacetoxyiodo)arene reacts with p-toluenesulfonamide in the presence of base to give the new type I–N ylide, N-tosyliminoaryliodinane. In the decomposition of this ylide, the nitrene intermediate is proposed to be formed and react with nucleophiles to afford the imine compounds.