荧光粉
发光
四方晶系
扫描电子显微镜
分析化学(期刊)
兴奋剂
白钨矿
材料科学
微晶
离子
铕
烧结
结晶学
晶体结构
化学
钨
冶金
光电子学
色谱法
复合材料
有机化学
标识
DOI:10.4028/www.scientific.net/amm.343.107
摘要
Red phosphors Eu 3+ - doped and Eu 3+ , Gd 3+ co-doped Na 2 Sr (MoO 4 ) 2 were prepared by sol-gel method, the crystal structural, morphology and composition were characterized by powder X-ray diffraction, and scanning electron microscope. The results showed that the synthesized Na 2 Sr (MoO 4 ) 2 : Eu 3+ , Gd 3+ crystallites with stability tetragonal scheelite structure after sintering temperature at 800°C. The particle size distributions of phosphor sample are irregular and the granule size about 0.5μm.The excitation and emission spectra were investigated that the influence of Gd 3+ ions on the luminescent properties of Eu 3+ in Na 2 Sr (MoO 4 ) 2 : Eu 3+ system. Luminescent intensity of Eu 3+ on the Na 2 Sr (MoO 4 ) 2 : Eu 3+ , Gd 3+ phosphor is much stronger than that of Eu 3+ single doped. It is indicated that the sensitizing effect of Gd 3+ for luminescence of Eu 3+ obviously. The highest excitation intensity of Na 2 Sr (MoO 4 ) 2 : Eu 3+ , Gd 3+ at 466 nm, matching the output wavelengths of blue LED chips.
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