八面体
刚度(电磁)
材料科学
热稳定性
结构稳定性
化学物理
结晶学
无机化学
化学工程
复合材料
化学
晶体结构
有机化学
结构工程
工程类
作者
Yang Liu,Hongpeng Zhou,Yongfeng Ni,Junxue Guo,Ruixue Lu,Can Li,Xin Guo
出处
期刊:Joule
[Elsevier]
日期:2023-05-01
卷期号:7 (5): 1016-1032
被引量:19
标识
DOI:10.1016/j.joule.2023.03.010
摘要
Dion-Jacobson (DJ) phase 2D perovskites have received wide attention due to their higher stability compared with 3D ones. However, some of the reported DJ 2D perovskites are not really robust, leading to a controversy over their stability. This necessitates clarification of the ambiguous stability mechanism. We herein elucidate that the stability of DJ 2D perovskites is determined by the rigidity of organic cations, which can induce co-adaptation of organic diammonium cations and inorganic [PbI6]4− octahedra to stabilize the 2D structure. By comparing three DJ 2D perovskites containing high-, medium-, and low-rigidity cations, we find that the medium-rigidity cation-based one presents higher structural stability. The finding is attributed to the appropriate cation rigidity, which enables organic diammoniums and inorganic octahedra to regulate their geometries to accommodate each other. This work explains the stability mechanism of DJ 2D perovskites and provides guidance for constructing highly stable candidates by adjusting the rigidity of organic cations.
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